SECTION 1. IDENTIFICATION
Product Name: Beryllium Foil
CAS #: 7440-41-7
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
Carc. 1B H350 May cause cancer.
STOT RE 1 H372 Causes damage to the lung and the blood through prolonged or repeated exposure.
Route of exposure: Inhalative.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
T+; Very toxic
R26: Very toxic by inhalation.
T; Toxic
R49-25-48/23: May cause cancer by inhalation. Toxic if swallowed. Toxic: danger of serious damage
to health by prolonged exposure through inhalation.Xi; Irritant
R36/37/38: Irritating to eyes, respiratory system and skin.
Xi; Sensitizing
R43: May cause sensitization by skin contact.
Carc. Cat. 2
Information concerning particular hazards for human and environment:
N/A
Hazards not otherwise classified
No data available
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms
GHS06 GHS08
Signal word: Danger
Hazard statements
H301 Toxic if swallowed.
H330 Fatal if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H335 May cause respiratory irritation.
H372 Causes damage to the lung and the blood through prolonged or repeated exposure. Route of
exposure: Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/...
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
WHMIS classification
D1A - Very toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1
0
0
Health (acute effects) = 1
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessmentPBT: N/A
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
7440-41-7 Beryllium
Identification number(s):
EC number: 231-150-7
Index number: 004-001-00-7
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
No special measures required.
If inhaled:
Seek medical treatment in case of complaints.
In case of skin contact:
Generally the product does not irritate the skin.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed:
Do not induce vomiting; immediately call for medical help.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Toxic metal oxide fume
Advice for firefighters
Protective equipment:
No special measures required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Do not allow product to enter drains, sewage systems, or other water courses.
Do not allow material to penetrate the ground or soil.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
No special measures required.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from strong bases.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace:
7440-41-7 Beryllium (100.0%)
PEL (USA) Long-term value: 0.002 mg/m
3
Ceiling limit value: 0.005; 0.025* mg/m
3
as Be; *30 min peak per 8-hr shift
REL (USA) Ceiling limit value: 0.0005 mg/m
3
as Be; See Pocket Guide App. ATLV (USA) Long-term value: 0.00005* mg/m
3
as Be;*inhalable; (SEN)NIC-DSEN;RSEN;Skin
EL (Canada) Long-term value: 0.002 mg/m
3
as Be; ACIGH A1, IARC 1
EV (Canada) Short-term value: 0.01 mg/m
3
Long-term value: 0.002 mg/m
3
as Be
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Not required.
Use self-contained respiratory protective device in emergency situations.
Protection of hands: Not required.
Penetration time of glove material (in minutes): No data available
Eye protection: Safety glasses
Body protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Solid in various forms
Color: Grey
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 1278 °C (2332 °F)
Boiling point/Boiling range: 2471 °C (4480 °F)
Sublimation temperature / start: No data available
Flammability (solid, gas): No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure at 990 °C (1814 °F): 0.000133 hPa
Density at 20 °C (68 °F): 1.848 g/cm
3
(15.422 lbs/gal)
Relative density: No data available.
Vapor density: N/A
Evaporation rate: N/A
Solubility in Water (H
2
O): Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No data available
Incompatible materials:
Acids
Bases
Hazardous decomposition products:
Toxic metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Fatal if inhaled.
Toxic if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this
substance.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion:
Generally the product does not irritate the skin.
Causes skin irritation.
Eye irritation or corrosion:
Causes serious eye damage.
Sensitization:
May cause an allergic skin reaction.
Germ cell mutagenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this
substance.
Carcinogenicity:
May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
ACGIH A1: Confirmed human carcinogen: Agent is carcinogenic to humans based on epidemiologic
studies of, or convincing clinical evidence in, exposed humans.
EPA-B1: Probable human carcinogen, limited evidence of carcinogenicity from epidemiologic studies.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or
carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure:
Causes damage to the lung and the blood through prolonged or repeated exposure. Route of
exposure: Inhalative.
Specific target organ system toxicity - single exposure:May cause respiratory irritation.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for
this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage
systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, ADN, IMDG, IATA
N/A
UN proper shipping name
DOT, ADN, IMDG, IATA
N/A
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATAClass
N/A
Packing group
DOT, IMDG, IATA
N/A
Environmental hazards:
N/A
Special precautions for user
N/A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7440-41-7 Beryllium
California Proposition 65
Prop 65 - Chemicals known to cause cancer
7440-41-7 Beryllium
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
Converters & Calculators
