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Flammability Vs Combustibility

Introduction to Inflammability

Inflammability is a critical property when assessing the safety and handling of materials. It determines the temperature at which a substance can readily ignite and sustain combustion. Knowledge of inflammability helps to prevent incidents and ensures the proper storage and utilisation of materials across various industries.

Inflammability vs. Combustibility

Although the terms inflammability and combustibility are often used interchangeably, they have distinct meanings:

Inflammability refers to the capacity of a material to ignite at relatively low temperatures. Inflammable materials catch fire easily and are generally associated with a greater risk in environments where ignition sources exist.

Combustibility describes materials that can burn, but which require higher temperatures to ignite. Combustible substances are typically regarded as less hazardous, although under certain conditions they can still present a fire risk.

Characteristics of Combustible Materials

Inflammable substances possess specific properties that make them susceptible to combustion:

  • Low flash point: The temperature at which a material vapourises sufficiently to form an ignitable mixture with air is low.
  • High vapour pressure: Indicates that the material releases vapours that can ignite easily.
  • Chemical structure: Certain molecular structures are more vulnerable to combustion.

An understanding of these properties is essential for the safe handling and storage of materials, thereby reducing the risk of fire.

Safety Measures for Handling Flammable Materials

To prevent accidents, it is essential to follow established safety protocols when handling flammable substances:

  • Storage: Store flammable materials in approved containers away from heat sources.
  • Ventilation: Ensure adequate ventilation to disperse vapours and reduce the risk of ignition.
  • Personal Protective Equipment (PPE): Use appropriate PPE to avoid exposure.
  • Fire suppression: Equip areas with suitable fire extinguishing systems, such as foam or dry chemical extinguishers.

Implementing these measures helps to mitigate the hazards associated with flammable substances.

Table of Inflammable and Combustible Materials

Table of Combustible Materials

Type

Material

Flash Point

Liquids

Petrol

-43°C / -45°F

Ethanol (Alcohol)

13°C / 55°F

Acetone

-20°C / -4°F

Methanol

11°C / 52°F

Diesel fuel

52°C / 126°F

Paint thinner

21°C / 70°F

Benzene

-11°C / 12°F

Lacquers and varnishes

15°C / 59°F

Solids

Wood charcoal dust

Varies by type

Magnesium powder

Easily ignitable

Sulphur

250°C / 482°F

White phosphorus

Ignites spontaneously in air

Gases

Hydrogen

-253°C / -423°F

Methane

-188°C / -306°F

Acetylene

-84°C / -119°F

Propane

-104°C / -155°F

Butane

-60°C / -76°F

Further details are available at Stanford Advanced Materials (SAM).

Table of Combustible Materials

Type

Material

Flash Point

Liquids

Kerosene

38°C / 100°F

Vegetable oils

320°C / 608°F

Engine oils

180°C / 356°F

Lubricants

160°C - 250°C / 320°F - 482°F

Coal tar

85°C / 185°F

Solids

Wood

~300°C / 572°F

Paper

230°C / 446°F

Cotton/Wool fabric

~250°C / 482°F

Rubber

~300°C / 572°F

Plastic (PVC, PET)

~300°C / 572°F

Gases

Carbon monoxide

N/A (flammable under certain conditions)

Natural gas

-188°C / -306°F

Further details are available at Stanford Advanced Materials (SAM).

Frequently Asked Questions

What is the principal difference between inflammability and combustibility?
Inflammability refers to the tendency of a material to ignite at lower temperatures, whereas combustibility denotes the capacity to burn when exposed to higher temperatures.

Can a material be both inflammable and combustible?
Yes, some materials exhibit both properties depending on the specific conditions and the presence of ignition sources.

Why is it important to identify combustible materials in industry?
Understanding combustible materials assists in implementing safety protocols to prevent fires and protect both personnel and property.

What are some common examples of combustible materials?
Examples include petrol, alcohol, acetone and certain types of solvents.

How can the fire risk associated with combustible materials be minimised?
The risk can be reduced by ensuring proper storage, sufficient ventilation, the use of personal protective equipment and the installation of appropriate fire suppression systems.

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About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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