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Hazard Codes & Pictograms

The Global Harmonised System

The Global Harmonised System (GHS) for Hazard Communication standardises the classification and labelling of chemicals. Its international implementation ensures that chemical hazard information remains consistent and is easily understood across different languages and regions. This system employs standardised hazard codes and pictograms to convey the severity and nature of chemical risks. Consequently, it facilitates a safer approach to chemical handling and use in workplaces worldwide.

OSHA Regulations on Hazard Pictograms

The Occupational Safety and Health Administration (OSHA) requires the use of specific hazard pictograms to protect employees from potential risks. The OSHA Hazard Communication Standard aligns with the GHS and requires employers to label chemicals with the appropriate pictograms that indicate hazard types such as flammability, toxicity or corrosivity. Compliance with OSHA standards ensures that employees are informed of chemical risks, thereby contributing to safer work environments.

Understanding Hazard Codes

Hazard codes are numerical or alphanumerical symbols that categorise the severity and type of chemical hazards. They provide a rapid reference for the potential risks of substances and assist in risk assessment and management. A code may indicate whether a chemical is flammable, irritating or harmful upon inhalation. When employees understand these codes, they can take appropriate safety precautions, such as using personal protective equipment or following designated handling procedures.

The Importance of Pictograms for Workplace Safety

Pictograms play a critical role in workplace safety by visually representing chemical hazards. They overcome language barriers so that every employee, irrespective of their first language, can recognise the risks. Their effective use contributes to accident prevention by providing immediate visual cues on necessary safety measures, for example, the need for ventilation, protective clothing or the prohibition of certain actions.

Table of Hazard Codes and Pictograms

Below is a table summarising the GHS hazard pictograms and corresponding codes:

Pictogram

Code(s)

Description

Health Hazard

H350, H360, H370, H372, H373

Indicates carcinogenic potential, reproductive toxicity or specific target organ toxicity.

Flame

H224, H226, H227, H228, H229

Identifies flammable liquids, solids, gases or self-heating substances.

Exclamation Mark

H332, H335, H336, H315, H317, H319

Indicates irritant properties, narcotic effects, respiratory irritation or irritation of the skin and eyes.

Gas Cylinder

H280

Denotes gas under pressure. If mishandled, it can cause explosion or rupture.

Corrosion

H314, H318, H332, H335

Indicates that the substance causes severe burns, eye damage or corrosive effects on materials.

Explosive

H201, H250, H260, H270

Denotes substances that are explosive, self-reactive or produce heat or explosive reactions with air or water.

Skull and Crossbones

H300, H301, H310, H330, H331

Indicates that the substance is fatal or toxic when swallowed, inhaled or absorbed.

Environmental (Aquatic)

H400, H410, H411, H412, H413

Indicates that the substance is extremely toxic, toxic or harmful to aquatic organisms, with long-lasting effects.

This table provides a quick overview of the GHS hazard pictograms and their associated codes. Each pictogram corresponds to a specific hazard group relating to health, fire or environmental risks. For further information, please refer to Stanford Advanced Materials (SAM).

Frequently Asked Questions

What is the Global Harmonised System (GHS)?
GHS is an international standard for the classification and labelling of chemicals. It ensures that hazard communication remains consistent worldwide.

How does OSHA enforce the use of hazard pictograms?
OSHA mandates that employers label chemicals with the appropriate GHS-compliant pictograms and provide safety training to employees.

Why are hazard codes important in the workplace?
They offer a rapid reference for identifying chemical hazards, assist in risk evaluation and ensure that appropriate safety measures are implemented.

Can pictograms be understood without language proficiency?
Yes, pictograms are designed to be universally recognisable. They facilitate effective hazard communication regardless of language.

How often should hazard labels be inspected or updated?
Labels should be inspected and updated when there is a change in the chemical’s hazard classification or the applicable safety standards.

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About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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