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What Is Surface Tension

Causes of Surface Tension

Surface tension enables a liquid’s surface to resist external forces, and it plays a role in various natural phenomena and technical processes.

Surface tension is primarily due to the cohesive forces between liquid molecules. In liquids such as water, hydrogen bonds generate significant intermolecular attractions, particularly at the surface. These forces result in a reduced exposed surface area and maintain the integrity of the liquid’s interface.

Measurement of Surface Tension

Accurate measurement of surface tension is essential for scientific research and industrial applications. Several methods are generally employed:

Capillary Rise Method

This technique measures the height a liquid ascends in a narrow tube due to surface tension. The measured height is directly related to the surface tension and can be calculated using established formulas.

Du Noüy Ring Method

In this method, a ring is carefully lowered onto the liquid surface and then lifted. The force required to detach the ring from the liquid is used as an indicator of the surface tension.

Wilhelmy Plate Method

A thin plate is immersed perpendicular to the liquid. The force exerted by the liquid’s surface tension on the plate is measured. This force is employed to determine the value of the surface tension.

Measurement Method

Description

Application

Capillary Rise

Measures the height of a liquid in a narrow tube

Research laboratories

Du Noüy Ring

Evaluates the force required to detach a ring from the liquid

Quality control in manufacturing

Wilhelmy Plate

Determines the force on an immersed plate

Materials science studies

For further information, please refer to Stanford Advanced Materials (SAM).

How to Reduce Surface Tension

To reduce surface tension, the cohesive forces between liquid molecules must be disrupted. Common approaches include:

  • Addition of Surfactants: Surfactants are compounds that reduce the surface tension by disrupting the hydrogen bonds between liquid molecules.
  • Increasing the Temperature: Heating a liquid weakens the intermolecular forces and thereby reduces the surface tension.
  • Mechanical Stirring: Stirring or shaking a liquid supplies energy that disrupts the surface layer, thereby reducing the surface tension.

Examples of Surface Tension in Nature and Technology

Surface tension is observed in various natural phenomena and technical applications:

  • Water Striders: These insects utilise surface tension to remain on top of water without sinking.
  • Formation of Droplets: Surface tension causes liquids to form spherical droplets, thereby minimising the exposed surface area.
  • Inkjet Printing: The formation and ejection of ink droplets depend on the precise control of surface tension.
  • Cleaning Agents: Surfactants in cleaning agents reduce surface tension and enhance the cleaning process by enabling water to spread and penetrate surfaces.

Frequently Asked Questions

What is surface tension?

Surface tension is the property of a liquid that enables its surface to resist external forces caused by cohesive forces between molecules.

How is surface tension measured?

Surface tension is measured using methods such as the capillary rise method, the Du Noüy ring method and the Wilhelmy plate method, each quantifying the force per unit length.

What causes surface tension in water?

In water, hydrogen bonds among the molecules generate cohesive forces that produce surface tension.

What effect do surfactants have on surface tension?

Surfactants reduce surface tension by disrupting the cohesive forces between liquid molecules, allowing liquids to spread and mix more readily.

Can temperature alter surface tension?

Yes, an increase in temperature generally reduces surface tension, given that the cohesive forces among the molecules are weakened.

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About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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