VO2958 Calcium Vanadate Powder (CAS 12135-52-3)

SECTION 1. IDENTIFICATION

Product Name: Calcium Vanadate

CAS #: 12135-52-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)

GHS06 Skull and crossbones

Acute Tox. 3 H331 Toxic if inhaled.

GHS08 Health hazard

Carc. 2

H351 Suspected of causing cancer.

Repr. 2

H361 Suspected of damaging fertility or the unborn child.

STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

STOT SE 3 H335 May cause respiratory irritation.

Hazards not otherwise classified

No data available

GHS label elements

GHS label elements, including precautionary statements

Hazard pictograms

GHS06 GHS08

Signal word: Danger

Hazard statements

H302 Harmful if swallowed.

H331 Toxic if inhaled.

H351 Suspected of causing cancer.

H361 Suspected of damaging fertility or the unborn child.

H335 May cause respiratory irritation.

H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statements

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P281

Use personal protective equipment as required.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

WHMIS classification

D1B - Toxic material causing immediate and serious toxic effects

D2A - Very toxic material causing other toxic effects

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

Health (acute effects) = 2

Flammability = 0

Physical Hazard = 0

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

14100-64-2 / 12135-52-3/ Calcium vanadium oxide

SECTION 4. FIRST AID MEASURES

Description of first aid measures

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol

resistant foam.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Toxic metal oxide fume

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Methods and materials for containment and cleanup:

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.Information about protection against explosions and fires:

The product is not flammable

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Do not store with interhalogens.

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Eye protection: Safety glasses

Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Powder

Color: Yellowish green

Odor: Odorless

Odor threshold: No data available.

pH: N/A

Melting point/Melting range: No data available

Boiling point/Boiling range: No data available

Sublimation temperature / start: No data available

Flash point: N/A

Flammability (solid, gas): No data available.

Ignition temperature: No data available

Decomposition temperature: No data available

Autoignition: No data available.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:Lower: No data available

Upper: No data available

Vapor pressure: N/A

Density: No data available

Relative density: No data available.

Vapor density: N/A

Evaporation rate: N/A

Solubility in Water (H

2

O): No data available

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: N/A

Kinematic: N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

No dangerous reactions known

Conditions to avoid

No data available

Incompatible materials:

No data available

Hazardous decomposition products:

Toxic metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Harmful if inhaled.

Harmful if swallowed.

LD/LC50 values that are relevant for classification: No data

Skin irritation or corrosion: Irritant to skin and mucous membranes.

Eye irritation or corrosion: Irritating effect.

Sensitization: No sensitizing effects known.

Germ cell mutagenicity: No effects known.

Carcinogenicity: Suspected of causing cancer.

Reproductive toxicity:

Suspected of damaging fertility or the unborn child.

Specific target organ system toxicity - repeated exposure:

Causes damage to organs through prolonged or repeated exposure.

Specific target organ system toxicity - single exposure:

May cause respiratory irritation.

Aspiration hazard: No effects known.Subacute to chronic toxicity:

Inhalation of magnesium compounds may cause metal fume fever.

Metallic magnesium which perforates the skin may cause local lesions. Some magnesium salts have

produced muscle weakness, cardiac arrhythmias, respiratory effects and changes in blood chemistry

following ingestion.

Subacute to chronic toxicity: No effects known.

Subacute to chronic toxicity:

Vanadium pentoxide is poisonous by ingestion and inhalation as well as other routes. Ingestion

causes disturbances of the gastrointestinal tract. May also cause apapular skin rash.

VanadiuInformation on toxicological effects

Acute toxicity:

Harmful if inhaled.

Harmful if swallowed.

LD/LC50 values that are relevant for classification: No data

Skin irritation or corrosion: Irritant to skin and mucous membranes.

Eye irritation or corrosion: Irritating effect.

Sensitization: No sensitizing effects known.

Germ cell mutagenicity: No effects known.

Carcinogenicity: Suspected of causing cancer.

Reproductive toxicity:

Suspected of damaging fertility or the unborn child.

Specific target organ system toxicity - repeated exposure:

Causes damage to organs through prolonged or repeated exposure.

Specific target organ system toxicity - single exposure:

May cause respiratory irritation.

Aspiration hazard: No effects known.

Subacute to chronic toxicity:

Subacute to chronic toxicity: No effects known.

Subacute to chronic toxicity:

Vanadium pentoxide is poisonous by ingestion and inhalation as well as other routes. Ingestion

causes disturbances of the gast rointestinal tract. May also cause apapular skin rash. Vanadium

pentoxide is a respiratory irritant. Effects include

skin pallor, greenish-black tongue, chest pain, cough, dsypnea, palpitation and lung changes. Causes

reproductive and mutagenic effects in laboratory animals.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully

known.pentoxide is a respiratory irritant. Effects include skin pallor, greenish-black tongue, chest pain,

cough, dsypnea, palpitation and lung changes. Causes reproductive and mutagenic effects in

laboratory animals.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data availableEcotoxical effects:

Remark:

Toxic for aquatic organisms

Additional ecological information:

Do not allow material to be released to the environment without official permits.

Toxic for aquatic organisms

Do not allow product to reach groundwater, water courses, or sewage systems, even in small

quantities.

Danger to drinking water if even extremely small quantities leak into the ground.

Also poisonous for fish and plankton in water bodies.

Toxic to aquatic life.

May cause long lasting harmful effects to aquatic life.

Avoid transfer into the environment.

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3285

UN proper shipping name

DOT

Vanadium compound, n.o.s. (Calcium vanadium oxide)

IMDG, IATA

VANADIUM COMPOUND, N.O.S. (Calcium vanadium oxide)

Transport hazard class(es)

DOT

Class

6.1 Toxic substances.

Label

6.1

Class

6.1 (T5) Toxic substances

Label

6.1

IMDG, IATA

Class

6.1 Toxic substances.Label

6.1

Packing group

DOT, IMDG, IATA

III

Environmental hazards:

Environmentally hazardous substance, solid

Special precautions for user

Warning: Toxic substances

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN3285, Vanadium compound, n.o.s. (Calcium vanadium oxide), 6.1, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

GHS GHS label elements, including precautionary statements

Hazard pictograms

GHS06

GHS08

Signal word: Danger

Hazard statements

H302 Harmful if swallowed.

H331 Toxic if inhaled.

H351 Suspected of causing cancer.

H361 Suspected of damaging fertility or the unborn child.

H335 May cause respiratory irritation.

H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statements

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P281

Use personal protective equipment as required.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

SARA Section 313 (specific toxic chemical listings)

14100-64-2 Calcium vanadium oxide

California Proposition 65

Prop 65 - Chemicals known to cause cancer

Substance is not listed.Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on themarket and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.