PB2554 Lead Zirconate (PbZrO3) Powder (CAS 12060-01-4)

SECTION 1. IDENTIFICATION

Product Name: Lead(II) Zirconate

CAS #: 12060-01-4

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)

GHS08 Health hazard

Repr. 1A H360 May damage fertility or the unborn child.

STOT RE 2 H373 May cause damage to the reproductive system, the blood, the brain and the

endocrine system through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H332 Harmful if inhaled.

Hazards not otherwise classified

No data available

GHS label elements

GHS label elements, including precautionary statements

Hazard pictograms

GHS07 GHS08

Signal word: Danger

Hazard statementsH302+H332 Harmful if swallowed or if inhaled.

H360 May damage fertility or the unborn child.

H373 May cause damage to the reproductive system, the blood, the brain and the endocrine system

through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

P281 Use personal protective equipment as required.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

WHMIS classification

D2A - Very toxic material causing other toxic effects

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

HEALTH

FIRE

REACTIVITY

2

0

0

Health (acute effects) = 2

Flammability = 0

Physical Hazard = 0

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

12060-01-4 Lead zirconium oxide

Identification number(s):

EC number: 235-039-4

Index number: 082-001-00-6

Additional information:

Zirconium is routinely found with a low level of hafnium since separation of the two elements is difficult.

SECTION 4. FIRST AID MEASURES

Description of first aid measures

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol

resistant foam.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Lead oxide fume

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Methods and materials for containment and cleanup:

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Open and handle container with care.

Information about protection against explosions and fires:No data available

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

No data available

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

Lead, elemental, and inorganic compounds (as Pb)

mg(Pb)/m3

ACGIH TLV 0.05; Confirmed animal carcinogen

Austria MAK 0.1

Belgium TWA 0.15

Denmark TWA 0.1

Germany MAK 0.1

Japan OEL 0.1

Korea TLV 0.05; Confirmed animal carcinogen

Netherlands TWA 0.15

Norway TWA 0.05

Poland TWA 0.05

Sweden TWA 0.05 (resp. dust)

0.1 (total dust)

Switzerland MAK-W 0.1

United Kingdom TWA 0.1

USA PEL 0.05

Zirconium and compounds, as Zr

mg/m3

ACGIH TLV 10; 10-STEL, Not classifiable as human carcinogen

Australia TWA 5; 10-STEL

Austria MAK 5

Denmark TWA 5

Finland TWA 5

Korea TLV 5

Hungary 5-STEL

Poland TWA 5; 10-STEL

Russia 6-STEL

OSHA PEL 5

Additional information: No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Refer to 29CFR1910.1025 for regulations on respiratory protection required during exposure to lead

and lead compounds.

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Eye protection: Safety glasses

Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Powder or crystals

Color: Light yellow

Odor: Odorless

Odor threshold: No data available.

pH: N/A

Melting point/Melting range: No data available

Boiling point/Boiling range: No data available

Sublimation temperature / start: No data available

Flash point: N/A

Flammability (solid, gas): No data available.

Ignition temperature: No data available

Decomposition temperature: No data available

Autoignition: No data available.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:

Lower: No data available

Upper: No data available

Vapor pressure: N/A

Density at 20 °C (68 °F): 7 g/cm

3

(58.415 lbs/gal)

Relative density: No data available.

Vapor density: N/A

Evaporation rate: N/A

Solubility in Water (H

2

O): Insoluble

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: N/A

Kinematic: N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

No dangerous reactions known

Conditions to avoid

No data available

Incompatible materials:

None known.

No data available

Hazardous decomposition products:

Lead oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Harmful if inhaled.

Harmful if swallowed.

LD/LC50 values that are relevant for classification: No data

Skin irritation or corrosion: Irritant to skin and mucous membranes.

Eye irritation or corrosion: Irritating effect.

Sensitization: No sensitizing effects known.

Germ cell mutagenicity: No effects known.

Carcinogenicity:

EPA-B2: Probable human carcinogen, sufficient evidence from animal studies; inadequate evidence or

no data from epidemiologic studies.

NTP-R: Reasonably anticipated to be a carcinogen: limited evidence from studies in humans or

sufficient evidence from studies in experimental animals.

ACGIH A3: Animal carcinogen: Agent is carcinogenic in experimental animals at a relatively high dose,

by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) not considered

relevant to worker exposure. Available epidemologic studies do not confirm an increased risk of

cancer in exposed humans.

Available evidence suggests that the agent is not likely to cause cancer in humans except under

uncommon or unlikely routes or levels of exposure.

IARC-2A: Probably carcinogenic to humans: limited human evidence; sufficient evidence in

experimental animals

Reproductive toxicity: May damage fertility or the unborn child.

Specific target organ system toxicity - repeated exposure:

May cause damage to the reproductive system, the blood, the brain and the endocrine system through

prolonged or repeated exposure. Route of exposure: Oral, Inhalative.

Specific target organ system toxicity - single exposure: No effects known.

Aspiration hazard: No effects known.

Subacute to chronic toxicity:

Lead and lead compounds may cause abdominal pain, diarrhea, loss of appetite, metallic taste,

nausea, vomiting, lassitude, insomnia, muscle weakness, joint and muscle pain, irritability, headache

and dizziness. Red blood cells may be damaged resulting in anemia. Gastritis and injury to the

kidneys, liver, male gonads, andcentral nervous system may also occur.Inhalation of zirconium and zirconium compounds may cause pulmonary granulomas.

Subacute to chronic toxicity: No effects known.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Ecotoxical effects:

Remark:

Very toxic for aquatic organisms

Additional ecological information:

Do not allow material to be released to the environment without official permits.

Do not allow product to reach groundwater, water courses, or sewage systems, even in small

quantities.

Danger to drinking water if even extremely small quantities leak into the ground.

Also poisonous for fish and plankton in water bodies.

May cause long lasting harmful effects to aquatic life.

Avoid transfer into the environment.

Very toxic for aquatic organisms

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3077

UN proper shipping name

DOTEnvironmentally hazardous substances, solid, n.o.s. (Lead zirconium oxide)

IMDG, IATA

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead zirconium oxide)

Transport hazard class(es)

DOT, IMDG

Class

9 Miscellaneous dangerous substances and articles.

Label

9

Class

9 (M7) Miscellaneous dangerous

substances and articles

Label

9

IATA

Class

9 Miscellaneous dangerous substances and articles.

Label

9

Packing group

DOT, IMDG, IATA

III

Environmental hazards:

Special marking (ADR):

Symbol (fish and tree)

Special marking (IATA):

Symbol (fish and tree)

Special precautions for user

Warning: Miscellaneous dangerous substances and articles

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN3077, Environmentally hazardous substances, solid, n.o.s. (Lead zirconium oxide), 9, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

GHS GHS label elements, including precautionary statements

Hazard pictograms

GHS07

GHS08

Signal word: Danger

Hazard statements

H302+H332 Harmful if swallowed or if inhaled.

H360 May damage fertility or the unborn child.

H373 May cause damage to the reproductive system, the blood, the brain and the endocrine system

through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray.P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

P281 Use personal protective equipment as required.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).

SARA Section 313 (specific toxic chemical listings)

12060-01-4 Lead zirconium oxide

California Proposition 65

Prop 65 - Chemicals known to cause cancer

12060-01-4 Lead zirconium oxide

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

This product contains lead and is subject to the reporting requirements of section 313 of the

Emergency Planning and Community

Right to Know Act of 1986 and 40CFR372.

Other regulations, limitations and prohibitive regulations

Refer to 29CFR1910.1025 for regulations concerning lead and lead compounds.

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.