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Magnetoelectric Polarizability: An Overview

Introduction

The magnetoelectric polarisability is a fundamental property in materials science and condensed matter physics. It describes the coupling between magnetic and electric fields within a material. Electric fields can induce a magnetic polarisation, and magnetic fields can induce an electric polarisation. Consequently, this property supports several research and industrial applications.

Magnetoelectric polarisability results from the intrinsic interactions between magnetic moments and electric dipoles in a material. When an external electric field is applied, it may produce a magnetic polarisation; likewise, an external magnetic field may induce an electric polarisation. This coupling is quantified by the magnetoelectric tensor, which characterises the strength and direction of the interaction.

Key Equation

One key equation describing this effect in such materials is:

P=χeϵ0E+αH

Where:

  • P is the electric polarisation (C/m²),
  • χe is the electric susceptibility (dimensionless),
  • ϵ0 is the vacuum permittivity (8,85×10⁻¹² C²/(N·m²)),
  • E is the electric field (V/m),
  • α is the magnetoelectric coupling coefficient (C-m/N-A), which quantifies the material’s sensitivity to the magnetic field,
  • H is the magnetic field strength (A/m).

Examples of Magnetoelectric Materials

Several materials exhibit significant magnetoelectric polarisability and are the subject of detailed investigation. Notable examples include:

  • Cr₂O₃ (Chromium(III) Oxide): One of the first materials observed to show magnetoelectric coupling.
  • BiFeO₃ (Bismuth Ferrite): A multiferroic material that exhibits both ferroelectric and antiferromagnetic orders.
  • TbMnO₃ (Terbium Manganite): Displays a complex magnetic ordering that leads to magnetoelectric effects.

Material

Magnetoelectric Coefficient (α)

Key Properties

Cr₂O₃

High

Antiferromagnetic; stable

BiFeO₃

Moderate

Multiferroic; piezoelectric

TbMnO₃

Variable

Complex magnetic ordering

For further information, please refer to Stanford Advanced Materials.

Applications of Magnetoelectric Polarisability

The distinct properties of magnetoelectric materials allow for a range of applications, including:

  • Sensors and Actuators: The coupling between electric and magnetic fields is exploited for precise control and detection.
  • Memory Devices: These materials offer potential for non-volatile memory, utilising the magnetoelectric effect for data encoding.
  • Spintronics: Electric fields can improve the manipulation of spin currents in electronic devices.

A precise understanding of the magnetoelectric coefficient is crucial for selecting suitable materials for specific applications. Higher values of α indicate a stronger coupling between electric and magnetic fields, thereby enhancing device performance.

Frequently Asked Questions

What is magnetoelectric polarisability?

Magnetoelectric polarisability is a property of a material that permits electric fields to induce a magnetic polarisation and magnetic fields to induce an electric polarisation.

Why is magnetoelectric polarisability important?

It enables the development of technologies, such as sensors, memory devices and spintronic applications, by providing a method to control magnetic behaviour via electric fields.

Does magnetoelectric polarisability occur in all materials?

No, it is observed only in certain materials that are identified as magnetoelectric or multiferroic, having both magnetic and electric orders.

How is magnetoelectric polarisability measured?

It is typically measured by applying electric and magnetic fields simultaneously and observing the induced polarisation or magnetisation.

What challenges exist regarding the use of magnetoelectric materials?

Challenges include finding materials that exhibit a sufficiently strong magnetoelectric coupling at room temperature and integrating these materials into existing technological systems.

About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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