PA3103 Dichloro(ethylenediamine)palladium(II) Powder PdCl2(H2NCH2CH2NH2) (CAS No.: 15020-99-2)

SECTION 1. IDENTIFICATION

Product Name: Dichloro(ethylenediamine)palladium(II)

CAS #: 15020-99-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

GHS Label elements, including precautionary statements

Pictogram

Signal word Warning

Hazard statement(s)

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Precautionary statement(s)

P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.

P264 Wash skin thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/ eye protection/ face protection.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position

comfortable for breathing.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/ physician if you feel unwell.

P321 Specific treatment (see supplemental first aid instructions on this label).

P332 + P313 If skin irritation occurs: Get medical advice/ attention.P337 + P313 If eye irritation persists: Get medical advice/ attention.

P362 Take off contaminated clothing and wash before reuse.

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Synonyms : Dichloro(ethylenediamine)palladium(II); Palladium(II) chloride ethylenediamine complex

Formula : C2H8Cl2N2Pd

Molecular Weight : 237.42 g/mol

CAS-No. : 15020-99-2

Hazardous components

Component Classification Concentration

Dichloro(ethylenediamine)palladium(II)

Skin Irrit. 2; Eye Irrit. 2A; -

STOT SE 3; H315, H319, H335

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous

area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a

physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labeling (see section 2.2) and/or

in

section 11

4.3 Indication of any immediate medical attention and special treatment needed

no data available

SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride gas

5.3 Advice for firefightersWear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

no data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure

adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection

see

section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed

containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust

ventilation at places where dust is formed.Normal measures for preventive fire protection. For

precautions

see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Store at room

temperature.

7.3 Specific end use(s)

no data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks

and at

the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and

approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated glovesafter use in accordance with applicable laws and Body Protection

Impervious clothing. The type of protective equipment must be selected according to the concentration

and amount of the dangerous substance at the specific workplace.

Respiratory protection

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level

protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use

respirators

and components tested and approved under appropriate government standards such as NIOSH (US)

or

CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a) Appearance Form: solid

b) Odor no data available

c) Odor Threshold no data available

d) pH no data available

e) Melting point/freezing point

Melting point/range: > 278 °C (> 532 °F) - lit.

f) Initial boiling point and boiling range no data available

g) Flash point no data available

h) EVaporation rate no data available

i) Flammability (solid, gas) no data available

j) Upper/lower flammability or explosive limits no data available

k) Vapor pressure no data available

l) Vapor density no data available

m) Relative density no data available

n) Water solubility no data available

o) Partition coefficient: noctanol/water no data available

p) Auto-ignition temperature no data available

q) Decomposition temperature no data available

r) Viscosity no data available

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

Other decomposition products - no data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as

a carcinogen or potential carcinogen by ACGIH.

NTP: No component of this product present at levels greater than or equal to 0.1% is identified as

a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as

a carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Additional Information

RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been

thoroughly investigated.

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity

no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed

professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US) IMDG IATA

Not dangerous goods Not dangerous goods Not dangerous goods

SECTION 15. REGULATORY INFORMATION

REACH No. : A registration number is not available for this substance as the substance or its uses are

exempted from registration, the annual tonnage does not require a registration or the registration is

envisaged for a later registration deadline.

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that

exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

Acute Health Hazard

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know Components

Dichloro(ethylenediamine)palladium(II) CAS-No. 15020-99-2

New Jersey Right To Know Components

Dichloro(ethylenediamine)palladium(II) CAS-No. 15020-99-2

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth

defects,

or any other reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.