EA2498 Bis (trifluoromethane) Sulfonimide Lithium Salt Powder C2F6LiNO4S2 (CAS No. 90076-65-6)

SECTION 1. IDENTIFICATION

Product Name: Bis(trifluoromethane)sulfonimide Lithium Salt

CAS #: 90076-65-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

GHS06 Skull and crossbones

Acute Tox. 3 H301 Toxic if swallowed.

Acute Tox. 3 H311 Toxic in contact with skin.

GHS08 Health hazard

STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Route of

exposure: Oral.

GHS05 Corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC

T; Toxic

R24/25: Toxic in contact with skin and if swallowed.

C; Corrosive

R34: Causes burns.

Xn; Harmful

R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed.

R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

Information concerning particular hazards for human and environment:N/A

Hazards not otherwise classified

No data available

Label elements

Labelling according to Regulation (EC) No 1272/2008

The substance is classified and labeled according to the CLP regulation.

Hazard pictograms

GHS05

GHS06

GHS08

Signal word

Danger

Hazard statements

H301+H311 Toxic if swallowed or in contact with skin.

H314 Causes severe skin burns and eye damage.

H373 May cause damage to organs through prolonged or repeated exposure. Route of exposure:

Oral.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/...

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with

water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P361 Take off immediately all contaminated clothing.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/

national/international regulations.

WHMIS classification

D1A - Very toxic material causing immediate and serious toxic effects

D2A - Very toxic material causing other toxic effects

E - Corrosive material

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

HEALTH

FIRE

REACTIVITY

3

1

1

Health (acute effects) = 3

Flammability = 1

Physical Hazard = 1

Other hazards

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

90076-65-6 Lithium bis(trifluoromethylsulfonyl)imide

Identification number(s):

ELINCS Number:

415-300-0

Index number:

616-124-00-9

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information

Immediately remove any clothing soiled by the product.

In case of irregular breathing or respiratory arrest provide artificial respiration.

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Do not induce vomiting; immediately call for medical help.

Information for doctor

Most important symptoms and effects, both acute and delayed

Causes severe skin burns.

Causes serious eye damage.

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol

resistant foam.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Carbon monoxide and carbon dioxide

Sulfur oxides (SOx)

Hydrogen fluoride (HF)

Nitrogen oxides (NOx)

Lithium oxide

Advice for firefighters

Protective equipment:

Wear self-contained respirator.Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Do not allow product to enter drains, sewage systems, or other water courses.

Do not allow material to penetrate the ground or soil.

Methods and materials for containment and cleanup:

Use neutralizing agent.

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Handle under dry protective gas.

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Prevent formation of dust.

Information about protection against explosions and fires:

No data available

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Store away from water/moisture.

Store away from oxidizing agents.

Further information about storage conditions:

Store under dry inert gas.

This product is moisture sensitive.

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Protect from humidity and water.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and

having an average face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values

that should be monitored at the workplace.

Additional information:

No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Avoid contact with the eyes and skin.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Recommended filter device for short term use:

Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls.

Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only

use equipment tested and approved under appropriate government standards.

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Material of gloves

Nitrile rubber, NBR

Penetration time of glove material (in minutes)

480

Glove thickness

0.11 mm

Eye protection:

Tightly sealed goggles

Full face protection

Body protection:

Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Powder

Color: White

Odor: Not determined

Odor threshold: Not determined.

pH: N/A

Melting point/Melting range: 234-238 °C (453-460 °F)Boiling point/Boiling range: Not determined

Sublimation temperature / start: Not determined

Flammability (solid, gas)

N/A

Ignition temperature: Not determined

Decomposition temperature: Not determined

Autoignition: Not determined.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:

Lower: Not determined

Upper: Not determined

Vapor pressure: N/A

Density: Not determined

Relative density

Not determined.

Vapor density

N/A

Evaporation rate

N/A

Solubility in Water (H

2

O): Soluble

Partition coefficient (n-octanol/water): Not determined.

Viscosity:

Dynamic: N/A

Kinematic: N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

Reacts with strong oxidizing agents

Conditions to avoid

No data available

Incompatible materials:

Oxidizing agents

Water/moisture

Hazardous decomposition products:

Carbon monoxide and carbon dioxide

Lithium oxide

Nitrogen oxides

Sulfur oxides (SOx)

Hydrogen fluoride

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Toxic in contact with skin.

Toxic if swallowed.

Danger through skin absorption.

Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation

of esophagus and stomach.

LD/LC50 values that are relevant for classification:

No data

Skin irritation or corrosion:

Causes severe skin burns.

Eye irritation or corrosion:

Causes serious eye damage.

Sensitization:

No sensitizing effects known.

Germ cell mutagenicity:

No effects known.

Carcinogenicity:

No classification data on carcinogenic properties of this material is available from the EPA, IARC,

NTP, OSHA or ACGIH.

Reproductive toxicity:

No effects known.

Specific target organ system toxicity - repeated exposure:

May cause damage to organs through prolonged or repeated exposure. Route of exposure: Oral.

Specific target organ is not known.

Specific target organ system toxicity - single exposure:

No effects known.

Aspiration hazard:

No effects known.

Subacute to chronic toxicity:

No effects known.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Ecotoxical effects:

Remark:

Harmful to aquatic organisms

Additional ecological information:

Do not allow material to be released to the environment without official permits.

Do not allow product to reach groundwater, water courses, or sewage systems, even in smallquantities.

Danger to drinking water if even extremely small quantities leak into the ground.

May cause long lasting harmful effects to aquatic life.

Avoid transfer into the environment.

Harmful to aquatic organisms

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

Recommended cleansing agent:

Water, if necessary with cleansing agents.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN2923

UN proper shipping name

DOT

Corrosive solids, toxic, n.o.s. (Lithium bis(trifluoromethylsulfonyl)imide)

IMDG, IATA

CORROSIVE SOLID, TOXIC, N.O.S. (Lithium bis(trifluoromethylsulfonyl)imide)

Transport hazard class(es)

DOT

Class

8 Corrosive substances.

Label

8+6.1

Class

8 (CT2) Corrosive substances

Label

8+6.1

IMDG, IATA

Class

8 Corrosive substances.

Label

8+6.1

Packing group

DOT, IMDG, IATAII

Environmental hazards: N/A

Special precautions for user

Warning: Corrosive substances

EMS Number: F-A,S-B

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information: DOT

Marine Pollutant (DOT): No

UN "Model Regulation":

UN2923, Corrosive solids, toxic, n.o.s. (Lithium bis(trifluoromethylsulfonyl)imide), 8(6.1), II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Domestic Substances List (DSL).

SARA Section 313 (specific toxic chemical listings)

Substance is not listed.

California Proposition 65

Prop 65 - Chemicals known to cause cancer

Substance is not listed.

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

REACH - Pre-registered substances

Substance is listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of theproperties of the product.