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  • Rhodium‐Catalysed Decarbonylative Borylation of Aromatic Thioesters for Facilitation of Diversification of Aromatic Carboxylic Acids

    • Rhodium‐Catalysed Decarbonylative Borylation of Aromatic Thioesters for Facilitation of Diversification of Aromatic Carboxylic Acids

    Title Rhodium‐Catalysed Decarbonylative Borylation of Aromatic Thioesters for Facilitation of Diversification of Aromatic Carboxylic Acids
    Authors Dr. Hidenori Ochiai, Dr. Yuta Uetake, Dr. Takashi Niwa, Prof. Dr. Takamitsu Hosoya
    Magazine Angewandte Chemie (International Ed. in English)
    Date 01/26/2017
    DOI 10.1002/anie.201611974
    Introduction The efficient transformation of aromatic thioesters into arylboronic esters is achieved through the use of a rhodium catalyst. This method, characterised by its broad functional-group tolerance and mild conditions, facilitates the two-step decarboxylative borylation of a variety of aromatic carboxylic acids, including those found in commercially available drugs.
    Quote Hidenori Ochiai, Yuta Uetake and Takashi Niwa et al. Rhodium‐Catalysed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids. Angew. Chem. Int. Ed. Engl. 2017. DOI: 10.1002/anie.201611974
    Element Rhodium (Rh)
    Materials Chemical Compounds
    Industry Chemical & Pharmacy
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