(1,5-Cyclooctadien)(methoxy)iridium(I) Dimer Powder Description
(1,5-Cyclooctadien)(methoxy)iridium(I)-dimer powder functions as a catalyst for C–H activation to synthesise phenols from arenes.
(1,5-Cyclooctadien)(methoxy)iridium(I) Dimer Powder Specification
CAS Number
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12148-71-9
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Molecular Formula
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[Ir(OCH3)(C8H12)]2
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Molecular Weight
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662.86 g/mol
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Synonyms
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Bis(1,5-cyclooctadien)di-µ-methoxydiiridium(I), [Ir(OMe)(1,5-cod)]2
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Appearance
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White Powder
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Melting Point
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154–179 °C
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(1,5-Cyclooctadien)(methoxy)iridium(I) Dimer Powder Application
(1,5-Cyclooctadien)(methoxy)iridium(I)-dimer powder can be used for:
- Synthesis of heteroaryl‐condensed indole ring systems as inhibitors of the HCV NS5B polymerase
- Borylation/Suzuki–Miyaura coupling
- Metallation–Suzuki cross-coupling procedures for the synthesis of biaryls and heterobiaryls
- Tetraborylation reactions
- Regioselective and enantioselective asymmetric hydroboration
- Ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives via C–H activation
(1,5-Cyclooctadien)(methoxy)iridium(I)-Dimer Powder Safety Information
Symbol
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GHS07
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Signal Word
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Warning
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Hazard Statements
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H315-H319-H335
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Precautionary Statements
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P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313
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Personal Protective Equipment
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Dust mask type N95 (US), eye protection, gloves
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RIDADR
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NONH for all transport modes
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WGK Germany
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3
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