SECTION 1. IDENTIFICATION
Product Name: Rhodium Sulfate Solution
CAS #: 10489-46-0
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Hazards not otherwise classified No data available.
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA
HCS)
Hazard pictograms
GHS05
Signal word Danger
Hazard-determining components of labeling:
Sulfuric acid
Rhodium(III) sulfate
Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy
to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3
0
1
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Mixtures
Dangerous components:
7664-93-9 Sulfuric acid Skin Corr. 1A, H314 25.0%
10489-46-0 Rhodium(III) sulfate Met. Corr.1, H290; Skin Corr. 1B, H314; Eye Dam. 1, H318 12.0%
Additional information None known.
Non-Hazardous Ingredients
7732-18-5 Water
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information Immediately remove any clothing soiled by the product.
If inhaled:
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact: Rinse opened eye for several minutes under running water. Consult a
physician.If swallowed: Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed No information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media Product is not flammable. Use fire-fighting measures that suit the
surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Sulfur oxides (SOx)
Rhodium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official
permits.
Methods and material for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure adequate ventilation.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.Information about storage in one common storage facility:
Store away from strong bases.
Store away from oxidizing agents.
Store away from reducing agents.
Store away from metal powders.
Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many
reactive organic
and inorganic chemicals.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s) No information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least
100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
7664-93-9 Sulfuric acid (25.0%)
PEL (USA) Long-term value: 1 mg/m³
REL (USA) Long-term value: 1 mg/m³
TLV (USA) Long-term value: 0.2* mg/m³
*as thoracic fraction
EL (Canada) Long-term value: 0.2 mg/m³
ACGIH A2; IARC 1
EV (Canada) Long-term value: 0.2 mg/m³
10489-46-0 Rhodium(III) sulfate (12.0%)
TLV (USA) Long-term value: 0.01 mg/m³
as Rh
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary
from
manufacturer to manufacturer.
Penetration time of glove material (in minutes) No data available.
Eye protection:
Tightly sealed gogglesFull face protection
Body protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Red-orange
Odor: Acidic
Odor threshold: No data available.
pH: No data available.
Melting point/range: No data available.
Boiling point/range: No data available.
Sublimation temperature / start: No data available.
Flammability (solid, gas): No data available.
Ignition temperature: No data available.
Decomposition temperature: No data available.
Auto igniting: Product is not selfigniting.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure at 20 °C (68 °F): 23 hPa (17 mm Hg)
Density at 20 °C (68 °F): 1.4 g/cm³ (11.683 lbs/gal)
Relative density No data available.
Vapor density No data available.
Evaporation rate No data available.
Solubility in / Miscibility with
Water: Fully miscible
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Solvent content:
Organic solvents: 0.0 %
Solids content: 12.0 %
Other information No information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity No data available.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored
according to
specifications.
Possibility of hazardous reactions
Water reacts violently with alkali metals.
Reacts with strong oxidizing agents
Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many
reactive organicand inorganic chemicals.
Conditions to avoid No information available.
Incompatible materials:
Bases
Oxidizing agents
Reducing agents
Metal powders
Hazardous decomposition products:
Sulfur oxides (SOx)
Rhodium oxide
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation
of esophagus and
stomach.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for
components in this
product.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Causes severe skin burns.
Eye irritation or corrosion: Causes serious eye damage.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains
mutation data for
components in this product.
Carcinogenicity:
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in
terms of its
carcinogenicity in humans and/or animals.
Reproductive toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains
reproductive data for
components in this product.
Specific target organ system toxicity - repeated exposure: N/A
Specific target organ system toxicity - single exposure: N/A
Aspiration hazard: N/A
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains
multiple dose
toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
The product shows the following dangers according to internally approved calculation methods for
preparations:
Corrosive
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity: No information available.
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility in soil: No information available.
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system.
Do not allow material to be released to the environment without official permits.
Danger to drinking water if even small quantities leak into the ground.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.
Other adverse effects No information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation: Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA UN3264
UN proper shipping name
DOT Corrosive liquid, acidic, inorganic, n.o.s. (Rhodium(III) sulfate, Sulfuric acid)
IMDG, IATA CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Rhodium(III) sulfate,
SULPHURIC ACID)
Transport hazard class(es)
DOT
Class 8 Corrosive substances.
Label 8
Class 8 (C1) Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances.
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant (IMDG): No
Special precautions for user Warning: Corrosive substances
EMS Number: F-A,S-B
Segregation groups AcidsTransport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3264, Corrosive liquid, acidic, inorganic, n.o.s. (Rhodium(III) sulfate,
Sulfuric
acid), 8, III
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA
HCS)
Hazard pictograms
GHS05
Signal word Danger
Hazard-determining components of labeling:
Sulfuric acid
Rhodium(III) sulfate
Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy
to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act
Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7664-93-9 Sulfuric acid 25.0%
California Proposition 65
Prop 65 - Chemicals known to cause cancer
None of the ingredients are listed.
Prop 65 - Developmental toxicity
None of the ingredients are listed.
Prop 65 - Developmental toxicity, female
None of the ingredients are listed.
Prop 65 - Developmental toxicity, male
None of the ingredients are listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.None of the ingredients are listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for
the manufacturing, placing on the
market and use must be observed.
None of the ingredients is listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
None of the ingredients is listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
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