PT3113 Dihydrogen Dinitrosulfatoplatinate(II) Solution

SECTION 1. IDENTIFICATION

Product Name: Dihydrogen Dinitrosulfatoplatinate(II) Solution

CAS #: 12033-81-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)

GHS05 Corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.

Hazards not otherwise classified

No data available

GHS label elements

GHS label elements, including precautionary statements

Hazard pictograms

GHS05

Signal word: Danger

Hazard-determining components of labeling:

Dihydrogen dinitrosulfatoplatinate(II)

Hazard statements

H314 Causes severe skin burns and eye damage.

Precautionary statements

P260

Do not breathe dust/fume/gas/mist/vapors/spray.P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.

Rinse skin with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

WHMIS classification

D2B - Toxic material causing other toxic effects

E - Corrosive material

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

Health (acute effects) = 3

Flammability = 0

Physical Hazard = 1

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Mixtures

Dangerous components:

7664-93-9 Sulfuric acid Skin Corr. 1A, H314 10.0%

12033-81-7 Dihydrogen dinitrosulfatoplatinate(II) Skin Corr. 1B, H314; Eye Dam. 1, H318 9.0%

Additional information: None known.

Non-Hazardous Ingredients

7732-18-5 Water 81.0%

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information

Immediately remove any clothing soiled by the product.

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

Causes severe skin burns.Causes serious eye damage.

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Product is not flammable. Use fire-fighting measures that suit the surrounding fire.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Sulfur oxides (SOx)

Nitrogen oxides (NOx)

Platinum oxide

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow product to enter drains, sewage systems, or other water courses.

Methods and materials for containment and cleanup:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Use neutralizing agent.

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Information about protection against explosions and fires:

The product is not flammable

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.Information about storage in one common storage facility:

Store away from strong bases.

Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many

reactive organic and inorganic chemicals.

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Additional information: No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Do not inhale dust / smoke / mist.

Avoid contact with the eyes and skin.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Recommended filter device for short term use:

Use a respirator with multi-purpose combination (US) or type ABEK (EN 14387) as a backup to

engineering controls. Risk assessment should be performed to determine if air-purifying respirators

are appropriate. Only use equipment tested and approved under appropriate government standards

such as NIOSH (USA) or CEN (EU).

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Material of gloves

Fluorocarbon rubber (Viton)

Penetration time of glove material (in minutes)

>480

Glove thickness

0.7 mm

Eye protection:

Tightly sealed goggles

Full face protection

Body protection:

Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical properties

Appearance:

Form: Liquid

Odor: No data available

Odor threshold: No data available.

pH: No data available.

Melting point/Melting range: No data available

Boiling point/Boiling range: No data available

Sublimation temperature / start: No data available

Flammability (solid, gas): No data available.

Ignition temperature: No data available

Decomposition temperature: No data available

Autoignition: Product is not selfigniting.

Danger of explosion: No data available.

Explosion limits:

Lower: No data available

Upper: No data available

Vapor pressure: No data available

Density: No data available

Relative density: No data available.

Vapor density: No data available.

Evaporation rate: No data available.

Solubility in Water (H

2

O): Not miscible or difficult to mix

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: No data available.

Kinematic: No data available.

Solvent content:

Organic solvents: 0.0 %

Solids content: 9.0 %

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many

reactive organic and inorganic chemicals.

Water reacts violently with alkali metals.

Conditions to avoid

No data available

Incompatible materials:

Bases

Hazardous decomposition products:

Sulfur oxides (SOx)

Nitrogen oxides

Platinum oxide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation

of esophagus and stomach.

The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for

components in this product.

LD/LC50 values that are relevant for classification: No data

Skin irritation or corrosion: Causes severe skin burns.

Eye irritation or corrosion: Causes serious eye damage.

Sensitization: No sensitizing effects known.

Germ cell mutagenicity:

The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for

components in this product.

Carcinogenicity:

No classification data on carcinogenic properties of this material is available from the EPA, IARC,

NTP, OSHA or ACGIH.

Reproductive toxicity:

The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for

components in this product.

Specific target organ system toxicity - repeated exposure: No effects known.

Specific target organ system toxicity - single exposure: No effects known.

Aspiration hazard: No effects known.

Subacute to chronic toxicity:

The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for

this substance.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

The product shows the following dangers according to internally approved calculation methods for

preparations: Corrosive

Carcinogenic categories

OSHA-Ca (Occupational Safety & Health Administration)

None of the ingredients is listed.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Additional ecological information:

Do not allow product to reach groundwater, water courses, or sewage systems.

Danger to drinking water if even small quantities leak into the ground.

Avoid transfer into the environment.

Results of PBT and vPvB assessmentPBT: N/A

vPvB: N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3264

UN proper shipping name

DOT

Corrosive liquid, acidic, inorganic, n.o.s. (Dihydrogen dinitrosulfatoplatinate(II),Sulfuric acid)

IMDG, IATA

CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

(Dihydrogendinitrosulfatoplatinate(II),SULPHURIC ACID)

Transport hazard class(es)

DOT

Class

8 Corrosive substances.

Label

8

Class

8 (C1) Corrosive substances

Label

8

IMDG, IATA

Class

8 Corrosive substances.

Label

8

Packing group

DOT, IMDG, IATA

III

Environmental hazards:

Marine pollutant (IMDG):

No

Special precautions for user

Warning: Corrosive substances

EMS Number:

F-A,S-B

Segregation groupsAcids

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN3264, Corrosive liquid, acidic, inorganic, n.o.s. (Dihydrogendinitrosulfatoplatinate(II), Sulfuric acid),

8, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

GHS GHS label elements, including precautionary statements

Hazard pictograms

GHS05

Signal word: Danger

Hazard-determining components of labeling:

Dihydrogen dinitrosulfatoplatinate(II)

Hazard statements

H314 Causes severe skin burns and eye damage.

Precautionary statements

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.

Rinse skin with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

The components of this product are listed on the Canadian Domestic

Substances List (DSL) and/or the Canadian Non-Domestic Substances List (NDSL).

SARA Section 313 (specific toxic chemical listings)

7664-93-9 Sulfuric acid

10.0%

California Proposition 65

Prop 65 - Chemicals known to cause cancer

None of the ingredients are listed.

Prop 65 - Developmental toxicity

None of the ingredients are listed.

Prop 65 - Developmental toxicity, female

None of the ingredients are listed.

Prop 65 - Developmental toxicity, male

None of the ingredients are listed.

Information about limitation of use:

For use only by technically qualified individuals.Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

None of the ingredients are listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

None of the ingredients is listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

None of the ingredients is listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.