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  • Bioorthogonal Azide–Thioalkyne Cycloaddition Catalysed by Photoactivatable Ruthenium(II) Complexes

    • Bioorthogonal Azide–Thioalkyne Cycloaddition Catalysed by Photoactivatable Ruthenium(II) Complexes

    Title Bioorthogonal Azide–Thioalkyne Cycloaddition Catalysed by Photoactivatable Ruthenium(II) Complexes
    Authors Alejandro Gutiérrez‐González, Dr. Paolo Destito, Dr. José R. Couceiro, Dr. Cibran Pérez‐González, Dr. Fernando López, Prof. José L. Mascareñas
    Magazine Angewandte Chemie (International Ed. in English)
    Date 06/16/2021
    DOI 10.1002/anie.202103645
    Introduction Ruthenium sandwich complexes with photoresponsive arene ligands can catalyse azide-thioalkyne cycloaddition (RuAtAC) under UV light exposure, facilitating bioorthogonal reactions in aqueous biological mixtures. This approach is applicable for selectively modifying biopolymers, such as DNA and peptides. Moreover, the ruthenium-based technique complements copper-catalysed azide-alkyne cycloaddition (CuAAC), allowing for mutually orthogonal processes.
    Quote Alejandro Gutierrez-Gonzalez, Paolo Destito and José R. Couceiro et al. Bioorthogonal Azide–Thioalkyne Cycloaddition Catalysed by Photoactivatable Ruthenium(II) Complexes. Angew. Chem. Int. Ed. Engl. 2021. DOI: 10.1002/anie.202103645
    Element Ruthenium (Ru)
    Materials Chemical Compounds , Biopolymers
    Industry Chemical & Pharmacy , Pharmaceutical Industry
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