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  • Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis

    • Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis

    Title Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
    Authors Rafał Gawin, Anna Kozakiewicz, Piotr A. Guńka, Paweł Dąbrowski, Krzysztof Skowerski
    Magazine Angewandte Chemie (International Ed. in English)
    Date 12/12/2016
    Introduction The modern approach in olefin metathesis leverages N-heterocyclic carbene (NHC)-containing ruthenium alkylidenes for creating internal C=C bonds, and cyclic alkyl amino carbene (CAAC)-containing ruthenium benzylidenes for producing terminal olefins. The newly reported synthesis of bis(CAAC)Ru indenylidene complexes demonstrates exceptional efficiency in forming both terminal and internal C=C bonds at minimal loadings of just 1 ppm.
    Quote Rafał Gawin, Anna M. Badowska-Kozakiewicz and Piotr A. Guńka et al. Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis. Angew. Chem. Int. Ed. Engl. 2016. DOI: 10.1002/anie.201609009
    Element Ruthenium (Ru)
    Materials Chemical Compounds
    Industry Chemical & Pharmacy
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