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BP10976 OH-PDLA-COOR, Medium Molecular Weight Grades, IV: 1–3 dl/g, Mw: 90–480 kDa

Catalogue Number BP10976
Composition OH-PDLA-COOR
Form Powder

OH-PDLA-COOR is a medium molecular weight grade from our hydroxyl- and ester-terminated poly(D-lactic acid) series. With an intrinsic viscosity between 1–3 dl/g and a molecular weight range of 90–480 kDa, this product features a hydroxyl group at one chain end and an ester group (-COOR) at the other. The D-configured backbone offers distinct stereocomplexation capability with PLLA, while the extended chain length provides enhanced mechanical properties compared to low molecular weight grades. Stanford Advanced Materials employs controlled polymerisation and precise end-capping techniques to ensure consistent molecular weight distribution, reliable end-group functionality, and excellent batch-to-batch reproducibility for demanding applications.

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FAQ

What are the key advantages of medium molecular weight OH-PDLA-COOR over its low molecular weight counterpart?

The medium molecular weight range (90–480 kDa) provides longer polymer chains with increased entanglement, resulting in significantly improved mechanical strength, higher melt viscosity, and more controllable, extended degradation profiles. This makes it suitable for applications requiring structural integrity and longer functional lifetimes, while retaining the stereocomplexation potential and end-group reactivity.

How does the ester-terminated end group (-COOR) benefit processing and application in medium molecular weight systems?

In medium molecular weight polymers, the -COOR group offers enhanced hydrophobicity and chemical stability, which is crucial for processing techniques requiring thermal stability (e.g., melt extrusion) and for applications in moisture-rich environments. It also provides a versatile site for controlled chemical modifications, such as grafting or crosslinking, to tailor material properties for specific uses.

What role does the D-lactide configuration play in the performance of this medium molecular weight grade?

The D-configured backbone is essential for forming high-performance stereocomplexes when blended with PLLA. This complexation can elevate the melting point to above 200°C, dramatically improving thermal stability and mechanical strength of the final material, making it ideal for applications demanding both high performance and biodegradability.

What are the primary application areas for medium molecular weight OH-PDLA-COOR?

This grade is ideally suited for medium-to-long-term biomedical implants (such as absorbable sutures and fixation devices), structural components in tissue engineering scaffolds, matrices for sustained drug delivery over weeks to months, and as a high-performance building block for creating stereocomplex-enhanced biodegradable materials for industrial and medical use.

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