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BP10980 OH-PDLA-OH, High Molecular Weight Grades, IV ≥ 3 dl/g, Mw ≥ 480 kDa

Catalogue Number BP10980
Composition OH-PDLA-OH
Form Powder

OH-PDLA-OH is a high molecular weight grade from our dihydroxy-terminated poly(D-lactic acid) series. Designed for applications requiring extended structural integrity and long-term performance, this product features an intrinsic viscosity ≥ 3 dl/g and a molecular weight ≥ 480 kDa. Its symmetrical dihydroxy structure and D-configured backbone provide a unique combination of high mechanical strength, stereocomplexation capability, and versatile end-group reactivity. Stanford Advanced Materials employs controlled high-viscosity polymerization and rigorous analytical methods to ensure consistent molecular weight distribution, precise end-group functionality, and reliable performance for advanced material engineering.

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FAQ

What types of applications are best suited for high molecular weight OH-PDLA-OH?

This grade is specifically designed for applications requiring long-term structural support, slow degradation, and high mechanical strength. Typical uses include long-term absorbable orthopaedic implants, high-load tissue engineering scaffolds, durable biodegradable packaging or prototypes, and as a building block for strong polymer networks that must maintain integrity for extended periods.

How do the dual hydroxyl end groups function in such high molecular weight systems?

Even at high molecular weights, the symmetrical dihydroxy termination remains highly reactive. It enables this polymer to serve as a macro-cross-linker or chain extender in the synthesis of strong, covalently bonded networks (e.g., polyurethanes, polyesters). This functionality is key to creating materials that combine the slow degradation of long chains with the tailored mechanical and chemical properties achievable through cross-linking.

What is the benefit of the D-lactide configuration in high molecular weight applications?

The D-configured backbone allows the polymer to form stereocomplexes when blended with PLLA. This interaction significantly enhances the thermal stability and mechanical performance of the resulting material, making it particularly valuable for applications exposed to higher temperatures or requiring improved durability, such as in certain industrial biodegradable composites or thermally stable medical devices.

Why are multiple sub-grades offered within the high molecular weight range?

Different sub-grades allow users to fine-tune the balance between mechanical strength, processability, and degradation rate for their specific application. For example, a grade around 480–730 kDa may offer an optimal balance for process-intensive device manufacturing, while a grade above 1700 kDa would be selected for applications demanding the highest mechanical integrity and longest degradation timeline, such as certain load-bearing implants.

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