VD0849 Lead Selenide (PbSe) Evaporation Materials

SECTION 1. IDENTIFICATION

Product Name: Lead Selenide

CAS #: 12069-00-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

GHS06 Skull and crossbones

Acute Tox. 2 H300 Fatal if swallowed.

Acute Tox. 2 H330 Fatal if inhaled.

GHS08 Health hazard

Repr. 1A H360 May damage fertility or the unborn child.

STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC

T; Toxic

R61-23/25: May cause harm to the unborn child. Toxic by inhalation and if swallowed.

Xn; Harmful

R62: Possible risk of impaired fertility.

N; Dangerous for the environment

R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

R33: Danger of cumulative effects.

Information concerning particular hazards for human and environment:

N/A

Hazards not otherwise classifiedNo data available

Label elements

Labelling according to Regulation (EC) No 1272/2008

The substance is classified and labeled according to the CLP regulation.

Hazard pictograms

GHS06

GHS08

Signal word

Danger

Hazard statements

H300+H330 Fatal if swallowed or if inhaled.

H360 May damage fertility or the unborn child.

H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P284 [In case of inadequate ventilation] wear respiratory protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/...

P320 Specific treatment is urgent (see on this label).

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/

national/international regulations.

WHMIS classification

D1A - Very toxic material causing immediate and serious toxic effects

D2A - Very toxic material causing other toxic effects

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

Health (acute effects) = 2

Flammability = 0

Physical Hazard = 1

Other hazards

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

12069-00-0 Lead(II) selenide

Identification number(s):

EC number:

235-109-4

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information

Immediately remove any clothing soiled by the product.

Remove breathing apparatus only after contaminated clothing has been completely removed.

In case of irregular breathing or respiratory arrest provide artificial respiration.

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Do not induce vomiting; immediately call for medical help.

Information for doctor

Most important symptoms and effects, both acute and delayed

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Special powder for metal fires. Do not use water.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Do not allow product to enter drains, sewage systems, or other water courses.

Do not allow material to penetrate the ground or soil.

Methods and materials for containment and cleanup:

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Open and handle container with care.

Information about protection against explosions and fires:

No data available

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Not required.

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

Lead, elemental, and inorganic compounds (as Pb)

mg(Pb)/m3

ACGIH TLV 0.05; Confirmed animal carcinogen

Austria MAK 0.1

Belgium TWA 0.15

Denmark TWA 0.1

Germany MAK 0.1

Japan OEL 0.1

Korea TLV 0.05; Confirmed animal carcinogen

Netherlands TWA 0.15

Norway TWA 0.05

Poland TWA 0.05

Sweden TWA 0.05 (resp. dust)

0.1 (total dust)

Switzerland MAK-W 0.1

United Kingdom TWA 0.1

USA PEL 0.05

Selenium and selenium compounds (as Se)

mg/m3

ACGIH TLV 0.2

Austria MAK 0.1Belgium TWA 0.2

Denmark TWA 0.1

Finland TWA 0.1; 0.3-STEL

Germany MAK 0.1

Hungary 0.1-STEL

Japan OEL 0.1

Korea TLV 0.2

Netherlands MAC-TGG 0.2

Poland TWA 0.1; 0.3-STEL

Sweden NGV 0.1

Switzerland MAK-W 0.1

United Kingdom TWA 0.1

USA PEL 0.2

Lead, elemental, and inorganic compounds (as Pb)

mg(Pb)/m3

ACGIH TLV 0.05 Confirmed animal carcinogen

Austria MAK 0.1

Belgium TWA 0.15

Denmark TWA 0.1

Germany MAK 0.1

Japan OEL 0.1

Netherlands TWA 0.15

Norway TWA 0.05

Poland TWA 0.05

Switzerland MAK-W 0.1

United Kingdom TWA 0.1

Finland TWA 0.1

France TWA 0.15

Hungary STEL 0.04

Sweden TWA 0.1 (total dust)

0.05 (resp. dust)

USA PEL 0.05

12069-00-0 Lead(II) selenide (100.0%)

PEL (USA) Long-term value: 0.2 mg/m

3

as Se

REL (USA) Long-term value: 0.2 mg/m

3

as Se

TLV (USA) Long-term value: 0.2 mg/m

3

as Se

EL (Canada) Long-term value: 0.05 mg/m

3

as Pb; IARC 2A, R

Ingredients with biological limit values:

12069-00-0 Lead(II) selenide (100.0%)

BEI (USA) 30 μg/100 ml

Medium: blood

Time: not critical

Parameter: Lead

Additional information:

No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Refer to 29CFR1910.1025 for regulations on respiratory protection required during exposure to lead

and lead compounds.

Refer to 29CFR1910.1025 for regulations on respiratory protection required during exposure to lead

and lead compounds.

Use self-contained respiratory protective device in emergency situations.

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Eye protection:

Safety glasses

Body protection:

Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Pieces or solid in various forms

Color: Grey

Odor: Product specific

Odor threshold: Not determined.

pH: N/A

Melting point/Melting range:1065 °C (1949 °F)

Boiling point/Boiling range: Not determined

Sublimation temperature / start: Not determined

Flash point: N/A

Flammability (solid, gas)

Not determined.

Ignition temperature: Not determined

Decomposition temperature: Not determined

Autoignition: Not determined.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:

Lower: Not determined

Upper: Not determined

Vapor pressure: N/A

Density at 20 °C (68 °F): 8.1 g/cm

3

(67.595 lbs/gal)

Relative density

Not determined.

Vapor density

N/A

Evaporation rate

N/A

Solubility in Water (H

2

O): Insoluble

Partition coefficient (n-octanol/water): Not determined.

Viscosity:Dynamic: N/A

Kinematic: N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

No dangerous reactions known

Conditions to avoid

No data available

Incompatible materials:

No data available

Hazardous decomposition products:

Toxic metal compounds

Hydrogen selenide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Fatal if inhaled.

Fatal if swallowed.

LD/LC50 values that are relevant for classification:

No data

Skin irritation or corrosion:

May cause irritation

Eye irritation or corrosion:

Irritating effect.

Sensitization:

No sensitizing effects known.

Germ cell mutagenicity:

No effects known.

Carcinogenicity:

No classification data on carcinogenic properties of this material is available from the EPA, IARC,

NTP, OSHA or ACGIH.

Reproductive toxicity:

May damage fertility or the unborn child.

Specific target organ system toxicity - repeated exposure:

May cause damage to organs through prolonged or repeated exposure.

Specific target organ system toxicity - single exposure:

No effects known.

Aspiration hazard:

No effects known.

Subacute to chronic toxicity:Lead and lead compounds may cause abdominal pain, diarrhea, loss of appetite, metallic taste,

nausea, vomiting, lassitude, insomnia, muscle weakness, joint and muscle pain, irritability, headache

and dizziness. Red blood cells may be damaged resulting in anemia. Gastritis and injury to the

kidneys, liver, male gonads, and central nervous system may also occur.

Selenium may cause amyotrophic lateral sclerosis, bronchial irritation,

gastrointestinal distress, vasopharyngeal irritation, garlic odor on breath and sweat, metallic

taste, pallor, irritability, excessive fatigue, loss of fingernails and hair, pulmonary edema, anemia and

weight loss.

Lead and lead compounds may cause abdominal pain, diarrhea, loss of appetite, metallic taste,

nausea, vomiting, lassitude, insomnia, muscle weakness, joint and muscle pain, irritability, headache

and dizziness. Red blood cells may be damaged resulting in anemia. Gastritis and injury to the

kidneys, liver, male gonads, and central nervous system may also occur.

Subacute to chronic toxicity:

No effects known.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Ecotoxical effects:

Remark:

Very toxic for aquatic organisms

Additional ecological information:

Do not allow material to be released to the environment without official permits.

Do not allow product to reach groundwater, water courses, or sewage systems, even in small

quantities.

Danger to drinking water if even extremely small quantities leak into the ground.

Also poisonous for fish and plankton in water bodies.

May cause long lasting harmful effects to aquatic life.

Avoid transfer into the environment.

Very toxic for aquatic organisms

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methodsRecommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3077

UN proper shipping name

DOT

Environmentally hazardous substances, solid, n.o.s. (Lead(II) selenide)

IMDG, IATA

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead(II) selenide)

Transport hazard class(es)

DOT, IMDG

Class

9 Miscellaneous dangerous substances and articles.

Label

9

Class

9 (M7) Miscellaneous dangerous substances and articles

Label

9

IATA

Class

9 Miscellaneous dangerous substances and articles.

Label

9

Packing group

DOT, IMDG, IATA

III

Environmental hazards:

Special marking (ADR):

Symbol (fish and tree)

Special marking (IATA):

Symbol (fish and tree)

Special precautions for user

Warning: Miscellaneous dangerous substances and articles

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN3077, Environmentally hazardous substances, solid, n.o.s. (Lead(II) selenide), 9, IIl

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Domestic Substances List (DSL).

This product contains a chemical known to the state of California to cause cancer and/or reproductive

toxicity.

SARA Section 313 (specific toxic chemical listings)

12069-00-0 Lead(II) selenide

California Proposition 65

Prop 65 - Chemicals known to cause cancer

12069-00-0 Lead(II) selenide

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

This product contains lead and is subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.

This product contains selenium and is subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.

This product contains lead and is subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.

Other regulations, limitations and prohibitive regulations

Refer to 29CFR1910.1025 for regulations concerning lead and lead compounds.

Refer to 29CFR1910.1025 for regulations concerning lead and lead compounds.

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

REACH - Pre-registered substances

Substance is listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.