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Nihonium: Element Properties And Uses

Description

Nihonium (Nh) is a highly radioactive artificially produced element with atomic number 113. It is very unstable, with isotopes that possess half-lives ranging from a few milliseconds to about 20 seconds. Due to its rapid decay, most of its chemical and physical properties are theoretically predicted and not yet established. Following periodic trends, Nihonium is a post-transition metal in group 13 with properties that resemble those of its lighter homologues, such as thallium.

Discovery of Nihonium

Nihonium was first synthesised in 2003 by researchers from Japan at the RIKEN lab. The scientists bombarded targets of bismuth-209 with zinc-70 ions, which produced Nihonium-278 atoms through a process of fusion. Alpha-particle spectroscopy was employed to identify the formed atoms, as they decayed almost immediately, emitting characteristic alpha particles.

The formal naming of Nihonium as an element was approved by IUPAC in 2015 and was officially named in 2016, with the name "Nihonium" derived from the Japanese term for Japan, "Nihon," in honour of the location of its discovery.

Isotopes and Stability

To date, several isotopes of Nihonium have been produced, with masses ranging from 278 to 286.

Isotope

Production Method

Half-Life

Decay Mode

Nihonium-278

⁷⁰Zn + ²⁰⁹Bi

~0.7 ms

Alpha decay

Nihonium-284

⁴⁸Ca + ²⁴³Am

~0.5 s

Alpha decay

Nihonium-286

Secondary decay chain

~20 s

Alpha decay, spontaneous fission

Nihonium-286 is the longest-lived currently known isotope, lasting sufficient time for chemical prediction and theoretical modelling. Researchers believe that elements near Nihonium might approach the "island of stability," a hypothesised region where superheavy nuclei would possess significantly extended half-lives.

Chemical Properties Description

Even with limited experimental data owing to Nihonium's short half-life, theoretical predictions provide a clear depiction:

Property

Predicted Value / Notes

Atomic Number

113

Most Stable Isotope

Nihonium-286

Half-life

20 seconds (Nihonium-286), <1 second for lighter isotopes

Electron Configuration

[Rn] 5f¹⁴6d¹⁰7s²7p¹

Density

~16–17 g/cm³ (predicted)

Melting Point

Unknown; estimated >700°C

Boiling Point

Unknown; expected >1400°C

Oxidation States

+1 and +3 likely; +3 comparable to thallium

Chemical Reactivity

Predicted to form halides and oxides; relativistic effects may lessen metallic character

For more information, please refer to Stanford Advanced Materials (SAM).

Notable Properties:

•      Due to its high atomic number, relativistic effects significantly impact its electron orbitals, potentially reducing reactivity compared to thallium.

• Expected to exhibit Nihonium(I) properties, such as TlCl, and Nihonium(III) properties, such as TlCl₃.

Methods of Preparation

Nihonium is synthesised in high-energy particle accelerators through heavy-ion nuclear fusion. The procedure involves:

1. Accelerating zinc-70 ions at high velocity.

2. Bombarding bismuth-209 targets to induce fusion, creating individual Nihonium nuclei.

3. Monitoring decays through alpha spectroscopy or automated nuclear detection arrays.

The preparation takes place in ultra-high vacuum conditions with precise beam alignment and highly sensitive detectors due to the rapid decay of the element.

Applications of Nihonium

Applications of Nihonium in technology are greatly limited because of its short half-life. However, its production has led to:

• Scientific Research: Nihonium provides insights into nuclear structure, the stability of superheavy elements, and relativistic effects on chemistry.

• Technological Advances: Technology and methodologies developed for its synthesis have progressed the fields in particle accelerator technology, nuclear detection techniques, and material analysis equipment.

• Isotope Production Methods: Techniques refined through Nihonium work lead to the production of artificial isotopes for industrial and medical purposes.

There are no industrial applications of the element itself, but the discovery contributes to fundamental materials and nuclear science research.

Frequently Asked Questions

What is Nihonium?

An artificially produced, short-lived, highly radioactive element (atomic number 113) with very short-lived isotopes.

How is Nihonium produced?

Through nuclear fusion within particle accelerators, typically by bombarding targets of bismuth with zinc ions.

What are its chemical properties?

Expected to be a post-transition metal with +1 and +3 oxidation states, possessing halides and oxides, with relativistic effects reducing reactivity.

Why is Nihonium not extensively useful?

Its rapid decay and extreme instability limit practical applications; its relevance is primarily in nuclear experimental science.

Are there industrial uses associated with Nihonium?

Although Nihonium itself is not used industrially, synthesis techniques and detection technology benefit nuclear science, isotope production, and advanced instrumentation technologies.

About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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