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Dielectric Constant: Common Materials And Solutions

Dielectric Constant of Common Materials

Material

Dielectric Constant

Air

1.00058986 ± 0.00000050
(at STP, 900 kHz)

Ammonia

26, 22, 20, 17 (-80, -40, 0, +20 °C)

Calcium Copper Titanate

>250 000

Carbon Disulphide

2.6

Concrete

4.5

Conjugated Polymers

1.8–6 to 100 000

Diamond

5.5–10

Electroactive Polymers

2–12

Ethylene Glycol

37

GaAs

12.4

Graphite

10–15

Hydrocyanic Acid

158.0–2.3 (0–21 °C)

Hydrofluoric Acid

175, 134, 111, 83.6
(-73, -42, -27, 0 °C),

Hydrogen Superoxide

128 aqueous –60
(-30–25 °C)

Melamine Resin

7.2–8.4

Methanol

30

Mica

3–6

Natural Rubber

7

Paper, Printing

1.4 (200 kHz)

Polyethylene/XLPE

2.25

PTFE/Teflon

2.1

Pyrex (Glass)

4.7 (3.7–10)

Salt

3–15

Sapphire

8.9–11.1 (anisotropic)

Silicon

11.68

Silicon Dioxide

3.9

Silicon Nitride

7–8 (polycrystalline, 1 MHz)

Silicone Rubber

2.9–4

Sulphuric Acid

84–100 (20–25 °C)

Vacuum

1

Water

87.9, 80.2, 55.5
(0, 20, 100 °C)
for visible light: 1.77

Note: The dielectric constants listed above were measured at room temperature under 1 kHz. [1]

Dielectric Constant of Common Solvents

Solvent

Dielectric Constant

Temperature

Acetal

3.7 – 3.9

298 K (25 °C)

Acetic Acid

6.2

293 K (20 °C)

Acetone

20.7

298 K (25 °C)

Acetonitrile

37.5

293 K (20 °C)

Acrylate

2.1–3.9

298 K (25 °C)

Benzene

2.3

298 K (25 °C)

Dichloromethane

9.1

293 K (20 °C)

Diethyl Ether

4.3

293 K (20 °C)

Dimethylformamide (DMF)

36.7

298 K (25 °C)

Ethanol

24.3

298 K (25 °C)

Ether

4.3

293 K (20 °C)

Fluorinated Refrigerant R-12

2

298 K (25 °C)

Fluorinated Refrigerant R-22

2

298 K (25 °C)

Formamide

109

293 K (20 °C)

Liquid Ammonia

17

273 K (0 °C)

Methanol

32.7

298 K (25 °C)

Nitromethane

35.9

303 K (30 °C)

Tetrahydrofuran (THF)

7.6

298 K (25 °C)

Water

78.4

298 K (25 °C)

Dielectric Constant: Frequently Asked Questions

1. What is the dielectric constant?

The dielectric constant, also known as the relative dielectric constant, measures the ability of a substance to store electrical energy in an electric field. It compares the capability of a material to insulate charges relative to a vacuum.

2. How is the dielectric constant calculated?

It is determined by dividing the capacitance of a capacitor filled with a substance by the capacitance of the same capacitor in a vacuum or in air. Mathematically, it is expressed as ε = C/C₀, where ε is the dielectric constant, C is the capacitance with the substance and C₀ is the capacitance in a vacuum.

3. Are the dielectric constant and breakdown strength the same?

No, they differ. The dielectric constant measures the ability of a material to store electrical energy, whereas the breakdown strength indicates the maximum electric field a material can withstand before electrical breakdown occurs.

4. Why is the dielectric constant important?

The dielectric constant is crucial in various fields. It is used in determining the behaviour of materials in electric fields, in designing capacitors, in understanding solvation effects in chemistry and in analysing material properties in electronics.

5. What affects the dielectric constant?

Factors such as molecular structure, polarity and intermolecular interactions significantly affect the dielectric constant of a substance. Polar substances typically have higher dielectric constants than non-polar substances.

6. Can the dielectric constant vary with temperature and pressure?

Yes, the dielectric constant may change with variations in temperature and pressure. Changes in these parameters can affect molecular interactions and thereby the ability of a substance to store electrical charge.

7. How does the dielectric constant affect solvation?

The dielectric constant influences a solvent's ability to dissolve ionic compounds. Solvents with a high dielectric constant are effective at dissociating ions and stabilising them.

8. What are some practical applications of dielectric constants?

Dielectric constants are applied in various industries. They are used in electronics for capacitor design, in chemistry for solvent selection, in materials science for understanding material properties and in the study of biomolecular interactions.

Reference:

[1] Relative Dielectric Constant. (23/11/2023). In Wikipedia. https://en.wikipedia.org/wiki/Relative_permittivity

About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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