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Coefficient Of Thermal Expansion

Coefficient of Thermal Expansion

The thermal expansion coefficient quantifies the extent to which a material’s dimensions change as the temperature varies. It is generally expressed in units per degree Celsius (°C⁻¹) or per Kelvin (K⁻¹). Although its precise description involves mathematical formulas, the principle refers to the linear, areal or volumetric changes that a material undergoes when its temperature fluctuates.

Factors Influencing Thermal Expansion

Several factors affect a material’s thermal expansion coefficient:

Material Composition

Different materials demonstrate distinct thermal expansion coefficients due to variations in their atomic and molecular structures. Metals, ceramics, polymers and composites respond based on their inherent structural properties.

Temperature Range

The coefficient can vary with the temperature. Some materials exhibit linear expansion within a certain temperature range, whereas others display non-linear behaviour at higher or lower temperatures.

Structural Anisotropy

Materials with anisotropic properties may expand differently along various axes. This aspect is particularly important for substances such as wood or specific crystals.

External Stresses

Existing stresses within a material can affect its expansion or contraction when the temperature changes. Stresses induced during manufacturing processes may alter the effective coefficient.

Environmental Effects

Exposure to factors such as moisture or chemicals can influence a material’s expansion properties over time.

Thermal Expansion of Common Materials

The following table lists examples of various materials and their corresponding thermal expansion coefficients:

Material

Thermal Expansion Coefficient (°C⁻¹)

Aluminium

23 ×10⁻⁶

Steel

12 ×10⁻⁶

Glass

9 ×10⁻⁶

Concrete

10 ×10⁻⁶

Copper

16.5 ×10⁻⁶

Brass

19 ×10⁻⁶

Titanium

8.6 ×10⁻⁶

Polyethylene

100 ×10⁻⁶

Carbon Fibre

0.5 ×10⁻⁶

Invar (Alloy)

1.2 ×10⁻⁶

Thermal Expansion of Common Metals

Metal

TAC (10⁻⁶/°C)

Aluminium

23.1

Brass

19–21

Phosphor Bronze

17.6

Copper

16.5

Gold

14.2

Iron

11.8

Lead

28.9

Magnesium

25.2

Nickel

13.3

Platinum

8.8

Silver

19.5

Stainless Steel (304)

16.0

Stainless Steel (316)

15.9

Carbon Steel

11.7–13.0

Tin

22.0

Titanium

8.6–9.4

Tungsten

4.5

Zinc

30.2

Zirconium

5.7

Frequently Asked Questions

What is the significance of the thermal expansion coefficient in engineering?

The thermal expansion coefficient is essential for designing structures and components that can accommodate temperature variations without experiencing excessive stress or deformation. It contributes to maintaining dimensional stability and ensuring the longevity of materials in practical applications.

How does the thermal expansion coefficient affect everyday objects?

Everyday objects such as bridges, railways and buildings expand and contract as the temperature changes. Understanding the thermal expansion coefficient enables engineers to design expansion joints and similar features to accommodate these dimensional variations, thereby preventing structural damage.

Can the thermal expansion coefficient be negative?

Yes, certain materials exhibit negative thermal expansion and contract when heated. These materials are uncommon and are utilised in specialised applications where controlled contraction is required.

How is the thermal expansion coefficient measured?

The coefficient is generally measured using techniques such as dilatometry. In these tests, the change in length or volume of a material is monitored while it is heated or cooled under controlled conditions.

Does the thermal expansion coefficient depend on material purity?

Impurities and alloying elements can significantly affect a material’s thermal expansion coefficient. Pure materials may exhibit expansion characteristics that differ from those of their alloyed counterparts.

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About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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