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The Corrosion Resistance Of Niobium Metal Against Metal Melts

Niob exhibits resistance to many metals and chemicals. Its high resistance is attainable at a low mass, and it can be formed at a relatively low temperature. Consequently, it can be processed into coloured coin inserts, corrosion‐resistant evaporation boats and diamond growth crucibles.

Niob is resistant to several metal melts such as Pb, Cd, Cs, Cu, Ga, Li and Mg. However, the material is not resistant to Al, Be, Ni, Zn and Co.

Corrosion Resistance Against Metal Melts

Aluminium

not resistant

Lithium

resistant at < 1 000 °C

Beryllium

not resistant

Magnesium

resistant at < 950 °C

Lead

resistant at < 850 °C

Sodium

resistant at < 1 000 °C

Cadmium

resistant at < 400 °C

Nickel

not resistant

Cesium

resistant at < 670 °C

Mercury

resistant at < 600 °C

Iron

not resistant

Silver

resistant at < 1 100 °C

Gallium

resistant at < 400 °C

Bismuth

resistant at < 550 °C

Potassium

resistant at < 1 000 °C

Zinc

not resistant

Copper

resistant at < 1 200 °C

Tin

not resistant

Cobalt

not resistant

Noble gases can be utilised as protective gases because Niob does not react with them. At elevated temperatures, Niob reacts with oxygen, nitrogen and hydrogen. Oxygen and nitrogen may be removed by annealing the material in a high vacuum at temperatures above 1 700 °C, while hydrogen is removed at approximately 800 °C. This process leads to a material loss due to the formation of volatile oxides and recrystallisation of the structure.

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