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Thermal Expansion Coefficient: Metals, Alloys, And Common Materials

Figure 1. Periodic Table [1]

Thermal Expansion Coefficient of Metals and Alloys

Metal

Thermal Expansion
(10-6 in/(in °F))

Admiralty Brass

11.2

Alumina

3

Aluminium

13.1

Aluminium Bronze

9.0

Antimony

5

Barium

11.4

Beryllium

6.7

Beryllium Copper

9.3

Bismuth

7.2

Brass

10.4

Bronze

10

Calcium

12.4

Grey Cast Iron

5.8

Steel Cast, 3% C

7.0

Cerium

2.9

Chromium

3.3

Cobalt

6.7

Copper

9.8

Copper-based Alloy – Manganese Bronze

11.8

Copper-based Alloy – Nickel Silver

9.0

Copper-Nickel

9.0

Erbium

6.8

Europium

19.4

Gadolinium

5

Germanium

3.4

Gold

7.9

Hafnium

3.3

Hastelloy C

5.3

Inconel

6.4

Incoloy

8.0

Indium

18.3

Invar

0.67

Iridium

3.3

Iron, Spheroidal Pearlitic

6.5

Pure Iron

6.8

Lead

15.1

Lithium

15.6

Magnesium

14

Manganese

12

Manganese Bronze

11.8

Structural Steel

5.9

Molybdenum

3.0

Monel

7.8

Neodymium

5.3

Nickel

7.2

Nickel Putty

7.4

Niobium

3.9

Red Brass

10.4

Osmium

2.8

Platinum

5

Plutonium

19.84

Potassium

46

Rhodium

4.4

Selenium

21

Silver

11

Sodium

39

Stainless Steel

9.4

Tantalum

3.6

Thorium

6.7

Terbium

5.7

Tin

12.8

Titanium

4.8

Tungsten

2.5

Uranium

7.4

Vanadium

4.4

Ytterbium

14.6

Zinc

19

Zirconium

3.2

Thermal Expansion Coefficient of Common Materials

Product

Thermal Expansion
(10-6 m/(m °C))

ABS (acrylonitrile–butadiene–styrene) thermoplastic polymer

72 – 108

ABS – Fibre-reinforced

31

Acetal – Fibre-reinforced

39

Acetal

85 – 110

Acrylic glass

68 – 75

Amber

50 – 60

Arsenic

4.7

Bleached Bakelite

22

Barium Ferrite

10

Benzocyclobutene

42

Brass

18 – 19

Brickwork

5

Bronze

17.5 – 18

Rubber

66 – 69

Grey Cast Iron

10.8

Celluloid

100

Cellulose Acetate (CA)

130

Cellulose Acetate Butyrate (CAB)

96 – 171

Cellulose Nitrate (CN)

80 – 120

Chlorinated Polyvinyl Chloride (CPVC)

63 – 66

Chromium

6 – 7

Mud Brick Structure

5.9

Concrete

13 – 14

Concrete Structure

9.8

Ebonite

70

Epoxy – Fibre-reinforced

36

Epoxy Resins, Casting Resins and Compounds, Unfilled

45 – 65

Ethylen–Ethylacrylate (EEA)

205

Ethylen–Vinylacetate (EVA)

180

Fluoroethylene–Propylene (FEP)

135

Fluorite, CaF2

19.5

Glass, Hard

5.9

Glass, Plate

9.0

Glass, Pyrex

4.0

Granite

7.9 – 8.4

Pure Graphite (Carbon)

4 – 8

Red Brass

18

Ice, 0°C Water

51

Inconel

11.5 – 12.6

Limestone

8

Macor

9.3

Marble

5.5 – 14.1

Masonry, Brick

4.7 – 9.0

Mica

3

Monel Metal

13.5

Mortar

7.3 – 13.5

Nylon, General Purpose

50 – 90

Nylon, Fibre-reinforced

23

Phosphor Bronze

16.7

Gypsum

17

Plastics

40 – 120

Polycarbonate – Fibre-reinforced

21.5

Polyester

124

Polyester – Fibre-reinforced

25

Polyethylene (PE)

108 – 200

Polyethylene (PE) – High Molecular Weight

108

Polyethylene Terephthalate (PET)

59.4

Polypropylene (PP), Unfilled

72 – 90

Polypropylene – Fibre-reinforced

32

Polytetrafluoroethylene (PTFE)

112 – 135

Polyvinyl Chloride (PVC)

54 – 110

Industrial Porcelain

4

Molten Quartz

0.55

Mineral Quartz

8 – 14

Sandstone

11.6

Sapphire

5.3

Wax

2 – 15

Wedgwood ware

8.9

Wood, Transverse (Perpendicular) to Grain

30

Wood, Fir

3.7

Wood, Parallel to Grain

3

Wood, Pine

5

Note: Most coefficients are measured at 25 °C (77 °F).

Thermal Expansion Coefficient: FAQs

1. What is the thermal expansion coefficient?

The thermal expansion coefficient refers to the rate at which a material expands or contracts in response to temperature changes. It quantifies the dimensional change of a material in response to temperature variations.

2. How is the thermal expansion coefficient measured?

Thermal expansion coefficients are typically determined using methods such as dilatometry or interferometry, whereby the material is subjected to controlled temperature changes, allowing the subsequent dimensional changes to be measured.

3. Why is the thermal expansion coefficient important?

Knowledge of the thermal expansion coefficient is crucial in various sectors, particularly in construction, engineering and materials science. It assists in predicting how materials respond to temperature fluctuations, thereby preventing structural damage or failure in applications subject to temperature changes.

4. Do all materials expand and contract at the same rate?

No, different materials exhibit varying thermal expansion coefficients. For instance, metals generally have higher coefficients than ceramics or polymers. Knowledge of these differences is essential for the selection of materials for specific applications.

5. How does thermal expansion affect structures?

Thermal expansion can cause dimensional changes in structures, resulting in stresses, deformations or cracks when materials expand or contract unevenly due to temperature variations. This phenomenon must be considered in architectural and engineering designs.

6. Can thermal expansion coefficients be controlled?

It is challenging to alter the inherent thermal expansion properties of a material; however, engineers and designers can mitigate the effects through design considerations, material selection and the use of composite materials with tailored properties.

7. Is thermal expansion always undesirable?

While thermal expansion may pose issues in some applications, it can be advantageous in others. For example, bimetal strips utilise different thermal expansion rates to function as thermometers or switches.

Reference:

[1] National Center for Biotechnology Information (2024). Periodic Table of the Elements. Accessed on 08/01/2024 from https://pubchem.ncbi.nlm.nih.gov/periodic-table/

About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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